NNFA Northwest Region
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Cats Claw(Uncaria tomentosa)
Alexander G. Schauss, PhDDirector, Life Sciences Division,
Introduction The Latin name for this herb is Uncaria tomentosa. The Spanish call it uña de gato, which translated into English is cats claw. The reference to a cats claw comes from the appearance of small hook-like appendices at the junction of this vines leaves. The Latin word for hook is uncus. Every member of the genus Uncaria has this distinctive characteristic. U. tomentosa (referred to as Cats Claw hereinafter) is a liana, or as we more commonly refer to it, a vine, that is an indigenous plant found in the eastern Andes mountains of Peru and Colombia, that has spread throughout tropical areas of Central and South America, including Panama, where it is considered a nuisance plant on many banana plantations. The vine is akin to a weed. It averages 25-30 feet in length, but can reach to lengths of over 200 feet when climbing up towering trees found in the forests of South America. The base of the vine can be as thick as a watermelon. Proponents of Cat's Claw have claimed that this new darling among herbal dietary supplements treats everything from malignant tumors to arthritis. This has stimulated considerable interest in this herb and, unfortunately, a number of unsubstantiated and even false myths that need to be dispelled. Table 1. List of Alkaloids Found In Cat's Claw (Uncaria tomentosa) (6)(1), (7) (8), (9), (10), (11), (12)(13)Therapeutic Constituents of Cats Claw Table 2 provides a list of the constituents found in Cats Claw, and their reported biological activity, potential therapeutic benefits, as adapted and expanded from a previous work on Cats Claw written by this author.(14)
Table 2 Some Biologically Active Chemicals Found In Cats Claw (Uncaria tomentosa)
Compound Biological Activity Beta-sitosterol (phytosterol) anti-inflammatory Campesterol (phytosterol) anti-inflammatory Catechins (tannins) anti-alcoholic, anti-arthritic, anti-cariogenic, anti-histaminic, anti-oxidant, anti- periodontal, anti-ulcer, cancer-preventive Dihydrocorynantheine (alkaloid) adrenergic blocker, hypotensive Glycosides metabolic regulation Hirsuteine (alkaloid) anti-hypertensive Hirsutine (alkaloid) myorelaxant, anti-hypertensive, hypotensive Isorhynchophylline (alkaloid) anti-hypertensive, hypotensive Mitraphylline (alkaloid) anti-hypertensive, hypotensive, myorelaxant, vasodilator Quercetin (flavonoid) anti-allergic, anti-anaphylactic, anti- asthmatic, anti-cataract, anti-diabetic, anti- viral, antitumor, cancer-preventive, anti- oxidant Quinovic acid glycoside Anti-viral, anti-inflammatory Rhynchophylline (alkaloid) anti-hypertensive, hypotensive, sedative, anti-inflammatory, vasodilator Rutin (flavonoid) anti-cataract, anti-dermatatic, anti-diabetic, anti-tumor, anti-viral, anti-oxidant Stigmasterol (phytosterol) anti-inflammatory
By reviewing Table 2, we can begin to confirm the wisdom of traditional healers who have used this herb to treat a diverse range of diseases and conditions, including cancer, arthritis, gastritis, and even some epidemic diseases. Cats Claw is sold as a dietary supplement in countries throughout the world. Since it is generally sold as a powder of the plant (root, bark, or root/bark), with all of its constituents intact, is gentle in its action. It tends to support the bodys own natural processes to restore balance. By comparison, a synthetic drug, by its very nature, forces a rapid change in metabolism which can and often does lead to some side effects.
Alkaloids in Cats Claw Alkaloids are among the most biologically active substances found in the plant kingdom. Many alkaloids can be potent therapeutic agents, while some can be highly toxic. For this reason, it is important to characterize (identify) all of the alkaloids in a plant being used for medicinal or food use. Alkaloids are usually classified according to their basic chemical structure. The most common classifications based on chemical structures are listed in Table 3. Some of the most important groups of alkaloids found in Cats Claw possessing therapeutic activities are shown in bold print.
Table 3. Classification of Major Alkaloids Imidazole Indole Isoquinoline Oxindole Piperidine Purine Pyridine Quinoline Steroidal structures Tropane
There are well over 5,000 alkaloids found in plants. Although they are not always easy to define in terms of their biological properties, they generally contain one or more nitrogen atoms per molecule, usually in a heterocyclic ring system, and possess pharmacological action, and by international convention end with the letters ine, with few exceptions. Caffeine, one of several xanthines (e.g. theobromide, theophylline) is a good example of an alkaloid most of us are familiar with. It is found in such foodstuffs as chocolate, tea and coffee. The xanthine, caffeine, is a purine alkaloid (2,6-dioxypurine) derived from the plant, Coffea arabica. Another example is quinine, a cinchona alkaloid that is an anti-malarial agent obtained from the bark of the Chinchona tree (Chinchona officinalis). A toxic alkaloid is strychnine, a plant alkaloid whose toxicity is well known. It is a modified corynane-type monoterpenoid indole alkaloid obtained from the dried, ripe seed of Strychnos nux-vomica, which in Latin means a nut that causes vomiting. One of the most interesting group of alkaloids found in Cats Claw, are the indole alkaloids, which are only found in three plant families, Apocyanaceae, Loganiaceae, and Rubiaceae. Within the family Rubiaceae is the genera, Uncaria, of which Uncaria tomentosa is a specific species. Indole alkaloids are widely distributed in nature and include such familiar compounds as tryptophan and serotonin. Plant species in the Rubiaceae family have a chemical in common, secolaganin, that is necessary for the production of two compounds, strictosidine and carboxystrictodine, required for the production of the indole and quinoline alkaloids. A second way to classify alkaloids is based on the specific amino acids they are derived from. Subdivisions of alkaloids can be based on amino acid precursors involved in alkaloid biosynthesis. The principal amino acid precursors that can result in these alkaloids are: anthranilic acid, histidine, lysine, nicotinic acid, ornithine, tyrosine, and tryptophan. Simply, plant alkaloids are derived from amino acids. In human metabolism, 20 different amino acids are commonly found in proteins, and each protein has a unique, genetically defined, amino acid sequence which determines its specific shape and function. They can serve as enzymes, hormones, immunoglobulins, and structural elements, in addition to being involved in oxygen transport, electron transport, muscle contractions, and numerous other activities. In plants they are involved in photosynthesis and a myriad of similar activities. The alkaloid, mitraphylline, found in U. tomentosa, is a hypotensive agent that acts as a weak central nervous system depressant.(15) The concentration of mitraphylline can vary depending on the part of the plant analyzed. Rhyncophylline is an alkaloid found in U. tomentosa that has been shown in mice, rats, and rabbits, to have inhibitory effects on platelet aggregation and thrombosis (thromboembolism).(16),(17) The formation of malondialdehyde (MDA) and the release of platelet factor 4 (PF4), suggest that this alkaloid has anti-thrombotic activity. With the exception of mitraphylline and rhynchophylline, the alkaloids in U. tomentosa have been shown to cause a pronounced enhancement of phagocytosis, in vitro and in vivo.(8) This partially explains its immunostimulatory reputation. But there are other important constituents in Cats Claw than alkaloids.
Flavonoids and Their Anti-oxidant Activity Cats Claw contains natural phenolic compounds called flavonoids. Flavonoids have been found to be important compounds found in many plant foods and herbs with a wide range of biological properties. For example, flavonoids can promote anti-oxidant activity. Flavonoids can spare the vitamin, ascorbic acid. Flavonoids can affect carcinogen metabolism by inhibiting the activities of tumor promoters involved in the process of carcinogenesis, including the hyperproliferation of cancer cells.(18)(19) Flavonoids can inhibit peroxidation of fats by trapping free-radicals.(20) Flavonoids can scavenge harmful free radicals such as hydroxyl and superoxide radicals.(21) This helps explain the anti-oxidant activity claims made for Cats Claw. Certainly one of the most provocative actions of Cats Claw is its ability to decrease the rate of cellular mutagenicity, a cancer-preventive property of the herb. In a previous work by this author, the case of two chronic smokers was used to illustrate how Cats Claw can dramatically decrease mutagenic activity within weeks of use. Nevertheless, further clinical studies are needed.
Condensed Polyphenolic Tannins and Their Anti-oxidant Activity Cats Claw contains condensed tannins, represented by such compounds as oligomeric proanthocyanidins (condensed tannins), leucoanthocyanidins, and polyphenols. In recent years, these compounds have been found to possess antioxidant activity.(22) Green tea (Camellia sinensis) is a good example of a plant that contains condensed tannins, whose polyphenolic flavonoid compounds are believed responsible for a lower incidence of some cancers in certain Asian populations.
Anti-viral Activity Claims that Cats Claw has anti-viral activity has attracted attention, particularly in relationship to some viral diseases. Glycosides in Cat's Claw have been shown to possess moderate anti-viral activity in vitro against the vesicular stomatitis virus and the rhinovirus type 1B (a flu virus).(9) However, the anti-viral effect occurred at relatively high concentrations with respect to the toxic dose... Whether the bark contains compounds which diminish the likelihood of side effects if taken at high doses is not known. (Adaptogens, such as Withenia somnifera, asphaltum, or Panax ginseng, are known to contain compounds which can reduce side effects.) This may explain why individuals taking the crude bark or root of Cats Claw powders have not reported nearly as many side effects as those subjects who have participated in drug efficacy trials involving isolated constituents.
Traditional History of Use of Cats Claw U. tomentosa is used as a remedy for various ailments among indigenous populations living in Latin America, especially tribal groups living in eastern Peru, such as the Ashaninka, Cashibo and Campa Indians. Members of the Ashaninka Indian living group are even employed today to harvest Cats Claw. Traditional Peruvian healers prepare decoctions of Cats Claw for the treatment of arthritis, intestinal infections, wound healing, some cancers and several epidemic diseases.(2) (23)(24) One of the earliest references to the use of Cats Claw in the English language was made by the botanist Millspaugh in 1892.(25)
How Should Cat's Claw by Prepared? The recommended intake of U. tomentosa is between two to five, 150 milligram, capsules a day on an empty stomach. Individuals experiencing gastrointestinal disturbance following the ingestion of the capsules should consider removing the contents of the capsules and mixing it in a cup of cold water. Slowly heat the water in a small pan for about ten minutes until it reaches the boiling point. When cool it can be consumed. Be forewarned: the taste is bitter. To prepare a decoction of Cats Claw, mix the fine powder with cold water and allow the mixture to simmer for 45 minutes on a stove at a temperature of 80 degrees Celsius. Decoctions are generally made in a strength of 30 grams (around one ounce) of powder to 800-850 milliliters (approximately one and one half pint) of water. Around 500 milliliters of simmered down liquid will be left. When cool the decoction is strained through filter paper. Like infusions, decoctions should be prepared fresh on a daily basis and kept in a tightly sealed bottle at room temperature. The adult dose is approximately 60 milliliters (two ounces) of the decoction mixed with 60 milliliters of water on an empty stomach. For children ages three to six, the dosage should be 20 milliliters of the tea with 20 milliliters of hot water. For older children, adjust accordingly. The decoction or encapsulated powder is taken three times a day. If side effects occur, such as diarrhea, reduce the frequency and dosage of the product. Generally, diarrhea is an indication that the dose is too high. However, the dose can be gradually increased over a two week period, use the bowel tolerance rule as an indicated of excessive intake.
References 1. Hemingway SR, Phillipson JD. Alkaloids from S. American species of Uncaria (Rubiaceae). Journal of Pharmacology and Pharmaceuticals 1974;26 (Suppl.):113. 2. Ostendorf FW. Nuttige planten en sierplanten in Suriname. Landbouw Proefstation in Suriname Bulletin 1962;79:199-200. 3. Yepez AM, De Ugaz OL, Alvarez CM, et al. Quinovic acid glycosides from Uncaria guianensis. Phytochemistry 1991:1635-1637. 4. Lavault M, Moretti C, Bruneton J. Alcaloides de I'Uncaria guianensis. Journal of Medicinal Plant Research 1983;47:244-245. 5. Press A. Popular herb thought to be poisonous. Austin (TX) Statesman 1995 September 5, 1995:B3. 6. de Matta SM, Monache DF, Ferrari F, Marini-Bettolo GB. Alkaloids and procyanidins of an Uncaria spp. from Peru. Farmaco-Scientifica 1975;31:527-535. 7. Laus G, Keplinger D. Separation of steroisomeric oxindole alkaloids from Uncaria tormentosa by high performance liquid chromatography. Journal of Chromotography A 1994;662:243-249. 8. Wagner H, Kreutzkamp B, Jurcic K. Die alkaloid von Uncaria tomentosa und ihre phagozytose-steigernde wirkung. (The alkaloids of Uncaria tomentosa and their phagocytosis-enhancing effect). Planta Medica 1985;47:419-423. 9. Aquino R, De Simone F, Pizza C. Plant metabolites. Structure and in vitro antiviral activity of quinovic acid glycosides from Uncaria tomentosa and Guettarda platypoda. Journal of Natural Products 1989;52:679-685. 10. Aquino R, De Simone F, Vincieri FF, Pizza C. New polyhydroxylated triterpenes from Uncaria tomentosa. Journal of Natural Products 1990;53:559-564. 11. Aquino R, De Feo V, De Simone F, Pizza C, Cirino G. Plant metabolites. New compounds and anti-inflammatory activity of Uncaria tomentosa. Journal of Natural Products 1991;54:453-459. 12. Stuppner H, Sturm S, Konwalinka G. HFLC analysis of the main oxindole alkaloids from Uncaria tormentosa. Chromatography 1992;31:597-600. 13. Stuppner H, Sturm S. Capillary electrophoretic analysis of oxindole alkaloids from Uncaria Tomentosa. Journal of Chromatography 1992:375-380. 14. Schauss AG. Cat's Claw. New Canaan, CT: Keats Publishing, 1996. 15. Harbone JB, Baxter H, eds. Phytochemical Dictionary: A Handbook of Bioactive Compounds from Plants. London: Taylor & Francis, 1993. 16. Jin RM, Chen CX, Li YK, Xu PK. Effect of rhynchophylline on platelet aggregation and experimental thrombosis. Acta Pharmacologica Sinica 1991;26:246-249. 17. Chang-Xun C, Ruo-Min J, Yi-Kui L, et al. Inhibitory effect of rhynchophylline on platelet aggregration and thrombosis. Acta Pharmacologica Sinica 1992;13:126-130. 18. Das A, Wang JH, Lien EJ. Carcinogenicity, mutagenicity and cancer preventing activities of flavonoids: A structural-system-activity relationship (SSAR) analysis. Progress in Drug Research 1994;42:133-166. 19. Dewick PM. Medicinal Natural Products: A Biosynthetic Approach. New York: John Wiley & Sons, 1998. 20. Khushbaktova ZA, Yusupova SM, Zamaraeva MV, et al. Interrelationships of the structures and antioxidant activities of some flavonoids from the plants of central asia. Chemistry of Natural Compounds 1996;32:338-343. 21. Larson RA. The antioxidants of higher plants. Phytochemistry 1988;27:969-978. 22. Ferreira D, Bekker R. Oligomeric proanthocyanidins: Naturally occurring O-heterocycles. Natural Products Report 1996;13:411-433. 23. Stuppner H, Sturm S, Geisen G, Zillian U, Konwalinka G. A differential sensitivity of oxindole alkaloids to normal and leukemic cell lines. Planta Med. 1993;Supplement Issue:A583. 24. Personal communication. , 1995. 25. Millspaugh CF. Medicinal Plants. Philadelphia: John C. Yorston & Company, 1892. |
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